Azo coupling in aromatic amines
I thought of two products that can be formed in azo coupling of aniline but can't decide which one is major so basically I need an answer to which product is major and why ? Thanks in advance😊
organic-chemistry reaction-mechanism
asked 2 hours ago
Aditya Garg
1293
add a comment |
I thought of two products that can be formed in azo coupling of aniline but can't decide which one is major so basically I need an answer to which product is major and why ? Thanks in advance😊
organic-chemistry reaction-mechanism
asked 2 hours ago
Aditya Garg
1293
Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago
add a comment |
I thought of two products that can be formed in azo coupling of aniline but can't decide which one is major so basically I need an answer to which product is major and why ? Thanks in advance😊
organic-chemistry reaction-mechanism
asked 2 hours ago
Aditya Garg
1293
I thought of two products that can be formed in azo coupling of aniline but can't decide which one is major so basically I need an answer to which product is major and why ? Thanks in advance😊
organic-chemistry reaction-mechanism
organic-chemistry reaction-mechanism
asked 2 hours ago
Aditya Garg
1293
asked 2 hours ago
Aditya Garg
1293
asked 2 hours ago
Aditya Garg
1293
asked 2 hours ago
Aditya Garg
1293
asked 2 hours ago
Aditya Garg
1293
1293
Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago
add a comment |
Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago
Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago
add a comment |
1 Answer
1
active
oldest
votes
This is a really interesting question and the answer is that the reaction of benzenediazonium chloride with aniline is a bit different to most of the reactions of benzenediazonium salts in that the initial product is the top compound diazoaminobenzene. It is possible to run the reaction to isolate diazoaminobenzene prep here. These diazoaminobenzene compounds are unstable with respect to reversion to a diazonium salt + nucleophile, and so many references suggest that the bottom product (4-aminoazobenzene) is directly produced. The procedure for the transformation of the diazaminobenzene to 4-aminoazobenzene is by heating to 50C with aniline prep here.
answered 1 hour ago
Waylander
5,79711021
add a comment |
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1 Answer
1
active
oldest
votes
1 Answer
1
active
oldest
votes
active
oldest
votes
active
oldest
votes
This is a really interesting question and the answer is that the reaction of benzenediazonium chloride with aniline is a bit different to most of the reactions of benzenediazonium salts in that the initial product is the top compound diazoaminobenzene. It is possible to run the reaction to isolate diazoaminobenzene prep here. These diazoaminobenzene compounds are unstable with respect to reversion to a diazonium salt + nucleophile, and so many references suggest that the bottom product (4-aminoazobenzene) is directly produced. The procedure for the transformation of the diazaminobenzene to 4-aminoazobenzene is by heating to 50C with aniline prep here.
answered 1 hour ago
Waylander
5,79711021
add a comment |
This is a really interesting question and the answer is that the reaction of benzenediazonium chloride with aniline is a bit different to most of the reactions of benzenediazonium salts in that the initial product is the top compound diazoaminobenzene. It is possible to run the reaction to isolate diazoaminobenzene prep here. These diazoaminobenzene compounds are unstable with respect to reversion to a diazonium salt + nucleophile, and so many references suggest that the bottom product (4-aminoazobenzene) is directly produced. The procedure for the transformation of the diazaminobenzene to 4-aminoazobenzene is by heating to 50C with aniline prep here.
answered 1 hour ago
Waylander
5,79711021
add a comment |
This is a really interesting question and the answer is that the reaction of benzenediazonium chloride with aniline is a bit different to most of the reactions of benzenediazonium salts in that the initial product is the top compound diazoaminobenzene. It is possible to run the reaction to isolate diazoaminobenzene prep here. These diazoaminobenzene compounds are unstable with respect to reversion to a diazonium salt + nucleophile, and so many references suggest that the bottom product (4-aminoazobenzene) is directly produced. The procedure for the transformation of the diazaminobenzene to 4-aminoazobenzene is by heating to 50C with aniline prep here.
answered 1 hour ago
Waylander
5,79711021
This is a really interesting question and the answer is that the reaction of benzenediazonium chloride with aniline is a bit different to most of the reactions of benzenediazonium salts in that the initial product is the top compound diazoaminobenzene. It is possible to run the reaction to isolate diazoaminobenzene prep here. These diazoaminobenzene compounds are unstable with respect to reversion to a diazonium salt + nucleophile, and so many references suggest that the bottom product (4-aminoazobenzene) is directly produced. The procedure for the transformation of the diazaminobenzene to 4-aminoazobenzene is by heating to 50C with aniline prep here.
answered 1 hour ago
Waylander
5,79711021
edited 47 mins ago
answered 1 hour ago
Waylander
5,79711021
answered 1 hour ago
Waylander
5,79711021
answered 1 hour ago
Waylander
5,79711021
5,79711021
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add a comment |
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Are you aware of the mechanism of the diazo coupling reaction?
– YUSUF HASAN
2 hours ago
Anyhow... Have a look at this
– YUSUF HASAN
1 hour ago
Can't realise how it helps??
– Aditya Garg
1 hour ago